Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag     

NING Chuanxiang  MA Zhongliang  JIANG Zhenxue  SU Siyuan  LI Tingwei  ZHENG Lunju  WANG Guozhen  LI Fengxun 《《地质学报》英文版》2020,94(2):352-363

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.  相似文献   

Forest operations,tree species composition and decline in rainfall explain runoff changes in the Nacimiento experimental catchments,south central Chile     

Andrés Iroumé  Julia Jones  James C. Bathurst 《水文研究》2021,35(6):e14257

Few long-term studies have explored how intensively managed short rotation forest plantations interact with climate variability. We examine how prolonged severe drought and forest operations affect runoff in 11 experimental catchments on private corporate forest land near Nacimiento in south central Chile over the period 2008–2019. The catchments (7.7–414 ha) contain forest plantations of exotic fast-growing species (Pinus radiata, Eucalyptus spp.) at various stages of growth in a Mediterranean climate (mean long-term annual rainfall = 1381 mm). Since 2010, a drought, unprecedented in recent history, has reduced rainfall at Nacimiento by 20%, relative to the long-term mean. Pre-drought runoff ratios were <0.2 under 8-year-old Eucalyptus; >0.4 under 21-year-old Radiata pine and >0.8 where herbicide treatments had controlled vegetation for 2 years in 38% of the catchment area. Early in the study period, clearcutting of Radiata pine (85%–95% of catchment area) increased streamflow by 150 mm as compared with the year before harvest, while clearcutting and partial cuts of Eucalyptus did not increase streamflow. During 2008–2019, the combination of emerging drought and forestry treatments (replanting with Eucalyptus after clearcutting of Radiata pine and Eucalyptus) reduced streamflow by 400–500 mm, and regeneration of previously herbicide-treated vegetation combined with growth of Eucalyptus plantations reduced streamflow by 1125 mm (87% of mean annual precipitation 2010–2019). These results from one of the most comprehensive forest catchment studies in the world on private industrial forest land indicate that multiple decades of forest management have reduced deep soil moisture reservoirs. This effect has been exacerbated by drought and conversion from Radiata pine to Eucalyptus, apparently largely eliminating subsurface supply to streamflow. The findings reveal tradeoffs between wood production and water supply, provide lessons for adapting forest management to the projected future drier climate in Chile, and underscore the need for continued experimental work in managed forest plantations.  相似文献   

Effects of changes in canopy interception on stream runoff response and recovery following clear-cutting of a Japanese coniferous forest in Fukuroyamasawa Experimental Watershed in Japan     

Tomoki Oda  Tomohiro Egusa  Nobuhito Ohte  Norifumi Hotta  Nobuaki Tanaka  Mark B. Green  Masakazu Suzuki 《水文研究》2021,35(5):e14177

Understanding changes in evapotranspiration during forest regrowth is essential to predict changes of stream runoff and recovery after forest cutting. Canopy interception (Ic) is an important component of evapotranspiration, however Ic changes and the impact on stream runoff during regrowth after cutting remains unclear due to limited observations. The objective of this study was to examine the effects of Ic changes on long-term stream runoff in a regrowth Japanese cedar and Japanese cypress forest following clear-cutting. This study was conducted in two 1-ha paired headwater catchments at Fukuroyamasawa Experimental Watershed in Japan. The catchments were 100% covered by Japanese coniferous plantation forest, one of which was 100% clear-cut in 1999 when the forest was 70 years old. In the treated catchment, annual runoff increased by 301 mm/year (14% of precipitation) the year following clear-cutting, and remained 185 mm/year (7.9% of precipitation) higher in the young regrowth forest for 12–14 years compared to the estimated runoff assuming no clear-cutting. The Ic change was −358 mm/year (17% of precipitation) after cutting and was −168 mm/year (6.7% of precipitation) in the 12–14 years old regrowth forest compared to the observed Ic during the pre-cutting period. Stream runoff increased in all seasons, and the Ic change was the main fraction of evapotranspiration change in all seasons throughout the observation period. These results suggest that the change in Ic accounted for most of the runoff response following forest cutting and the subsequent runoff recovery in this coniferous forest.  相似文献   

Multi-stage metasomatism of lithospheric mantle by asthenosphere-derived melts: evidence from mantle xenoliths in daxizhuang at the eastern North China craton     

Zhao  XinMiao  Wang  Hui  Li  ZhiHan  Liu  FengLin  Evans  Noreen J.  Zhang  HongFu 《Mineralogy and Petrology》2020,114(2):141-159

Mineralogy and Petrology - A detailed study on petrology and mineral chemistry of 12 mantle xenoliths from Late Cretaceous basaltic lava flows at Daxizhuang has been conducted to constrain the...  相似文献   

北京十三陵地区青白口系长龙山组含铁建造的发育特征及成因^*          下载免费PDF全文

张琴  王柏寒  周琛  孙祖宇  梅啸寒  原成帅  王凯 《古地理学报》2020,22(3):570-586

含铁建造在整个前寒武纪的地质记录中分布广泛,但针对华北地区青白口系长龙山组出露的含铁建造目前还没有报道。文中通过野外观察及室内XRD、SEM、ICP-MS等手段,对北京十三陵地区出露的长龙山组含铁建造的分布规律、矿物组成、成矿物质来源等开展研究,并探讨含铁建造的成因机制。结果表明,含铁建造的铁质主要为赤铁矿,与石英、海绿石等矿物伴生。含铁建造存在2种分布模式: Ⅰ型含铁建造,与海绿石伴生,产出厚度变化大(1~50 cm),偏光显微镜下海绿石砂岩和铁质条带呈互层状产出,赤铁矿具近球形结构;Ⅱ型含铁建造,无海绿石伴生,产出厚度相对较大(一般大于10 cm),镜下见黑色的富铁层夹碎屑石英透镜体,赤铁矿常发育针状或雪花状结构。依据构造演化和微量元素分析,认为含铁建造的铁质来源主要为下马岭组顶部的铁质风化壳。Ⅰ型含铁建造为化学胶体沉淀与海绿石风化的混合成因;Ⅱ型含铁建造主要属于胶体化学沉积成因,后期可能经受了糜棱化改造作用。这一结论为华北地区前寒武纪含铁建造的找矿提供了沉积地质依据,对于完善含铁建造成矿机理及华北地区元古代构造演化具有重要的意义。  相似文献   

小兴安岭-张广才岭铁力地区侏罗纪辉绿岩年代学、地球化学、锆石Hf同位素特征及其构造意义   总被引：1，自引：0，他引：1  

葛茂卉  张进江  刘恺 《岩石学报》2020,36(3):726-740

小兴安岭-张广才岭地区中生代岩浆活动的成因及动力学背景对于揭示古太平洋的构造演化具有重要意义。本文选取小兴安岭-张广才岭铁力地区出露的辉绿岩墙为研究对象,进行锆石LA-ICP-MS U-Pb年代学、全岩地球化学和锆石Hf同位素等分析,对该基性岩的形成时代、岩石成因、岩浆源区以及形成的大地构造背景进行讨论。研究表明:辉绿岩锆石具有高Th/U比值( 0.3),CL图像显示微弱的振荡环带结构,具有岩浆锆石特征,~(206)Pb/~(238)U加权平均年龄为187±2Ma,即形成于早侏罗世;该岩体主要经历了橄榄石和单斜辉石的分离结晶作用,未遭受明显的地壳混染作用,并且具有Rb、Ba、U、Pb、K和Sr等流体活动元素相对富集,Th、Nb和Ta等非流体活动性元素相对亏损的地球化学特征,暗示其形成于被俯冲流体富集交代的亏损地幔部分熔融,源区可能为尖晶石-石榴石二辉橄榄岩,部分熔融程度约为6%～20%。结合该地区同时代的岩浆岩、变形构造、矿床特征和黑龙江蓝片岩的相关报道,本文认为小兴安岭-张广才岭地区在中生代期间处于活动大陆边缘环境,其岩浆岩的形成主要是由于存在于佳木斯地块和松嫩-小兴安岭地块间的牡丹江洋西向俯冲造成的。  相似文献   

塔里木盆地苏盖特布拉克剖面寒武系第二统第三阶微生物岩结构类型^*          下载免费PDF全文

李莹  潘文庆  吴亚生  杨果  孙崇浩  姜红霞 《古地理学报》2020,22(4):663-679

塔里木盆地阿克苏地区寒武系第二统第三阶肖尔布拉克组主要由微生物白云岩组成,代表性的剖面在阿克苏市西南90 km处的苏盖特布拉克。由于成岩作用改造严重,对这套微生物碳酸盐岩的特征和形成环境的认识还存在很多分歧,制约了勘探工作。通过详细野外勘察和室内研究,将肖尔布拉克组微生物岩分为4种结构类型: 凝块结构、纹层结构、砂屑结构和骨架结构。首次对凝块结构和纹层结构进行了亚类型的划分,其中凝块结构可划分为蠕虫状、网状和斑点状3种亚类型,纹层结构可划分为致密纹层、短薄纹层、颗粒纹层以及单纹层、纹层组、复合纹层。肖Ⅰ段—肖Ⅲ段发育凝块石白云岩、凝块—层纹石白云岩和层纹石白云岩,肖Ⅳ段发育凝块石微生物丘,肖V段下部发育网状结构凝块石白云岩,肖V段上部发育砂屑白云岩和肾形菌骨架岩。白云石化作用、溶蚀作用、重结晶作用是改变肖尔布拉克组微生物岩结构最重要的成岩作用,且该组下部比上部遭受了更强的成岩作用改造;微生物岩结构对成岩作用改造的抵抗能力为: 砂屑结构>纹层结构>凝块结构。根据微生物岩结构,推测肖Ⅰ段—肖Ⅲ段形成于潮坪环境,肖Ⅳ段和肖V段下部形成于深水潮下环境,肖V段上部形成于浅水潮下环境。以上成果为认识塔里木盆地肖尔布拉克组微生物岩的平面分布规律和今后开展被成岩作用强烈改造的白云岩型微生物岩的研究提供了一个重要参考。  相似文献   

A near-inertial current event in the homogeneous deep layer of the northern Sea of Japan during winter     

Michio Watanabe  Toshiyuki Hibiya 《Journal of Oceanography》2018,74(2):209-218

Under strong surface wind forcing during winter, direct current observations in the northern Sea of Japan show the existence of strong near-inertial currents in the deep water that is characterized by the extremely homogeneous vertical structures of temperature and salinity. However, the mechanism generating internal waves in the deep water of the northern Sea of Japan has not been well understood. In this study, to clarify the dynamical link between the surface wind forcing and near-inertial currents in the deep water of the northern Sea of Japan, we drive a general circulation model taking into account realistic wind stress, ocean bottom and land topography. In the northern Sea of Japan, the numerical results show that vertically coherent horizontal currents with a speed of ~ 0.05 m s^?1 are excited throughout the homogeneous deep water. A two-layer model successfully reproduces the pattern of the horizontal current velocities shown by the general circulation model, indicating that internal waves emanate westward from the northwestern coast of Japan through coastal adjustment to the strong wind forcing event and, while propagating into the ocean interior, they excite evanescent near-inertial response throughout the lower layer below the interface.  相似文献   

Two generations of Variscan garnet: Implications from a petrochronological study of a high-grade Avalonia-derived paragneiss from the Drosendorf unit,Bohemian Massif     

《Gondwana Research》2020

Garnets in metapelitic paragneisses from the southern Drosendorf unit in the Austrian part of the Bohemian Massif exhibit two episodes of growth during the Variscan orogeny, which can be distinguished on textural and chemical grounds. The first garnet (grt1) records evidence of high-grade metamorphism in the Late Devonian (Frasnian–Famennian), while the second garnet (grt2) formed by a second high-grade event in the Early Carboniferous (Visean). Both garnet generations contain abundant inclusions, of which monazite, rutile and crystallised melt droplets are particularly useful for reconstructing P–T–t conditions. The Late Devonian age (373 ± 9 Ma) for the first episode of garnet growth was obtained from chemical dating of monazite inclusions in grt1. Metamorphic conditions during the first episode of garnet growth are estimated to have been between 0.7 and 0.8 GPa at 680–700 °C and 0.95–1.10 GPa at 745–785 °C. There followed a phase of cooling and exhumation, after which the second garnet (grt2) were formed beginning under amphibolite facies conditions and continuing prograde to peak conditions of 0.95–1.10 GPa and 745–785 °C, which are similar to those of the first garnet forming event. Subsequently, the rocks experienced near isothermal decompression to 0.5–0.8 GPa. Chemical dating of both monazite inclusions in grt2 and the matrix provide a Visean age (343 ± 3 Ma).A study of detrital zircons in these paragneisses revealed zircon forming events at around 1.2, 1.5 and 1.8 Ga, suggesting an Avalonian provenance. The lack of zircons younger than 1 Ga and the presence of Cadomian metamorphic monazite relics (652 ± 15 Ma) indicates an Early Neoproterozoic deposition age for the sedimentary protolith likely. Our documentation of a Late Devonian high-grade metamorphic event in rocks derived from Avalonian corroborates tectonic models which assume that frontal parts of the Armorican terrane had already docked with Avalonia by this time.  相似文献   

Middle Permian organic carbon isotope stratigraphy and the origin of the Kamura Event     

《Gondwana Research》2020

Large carbon cycle perturbations associated with the Middle Permian (Capitanian) mass extinction have been widely reported, but their causes and timing are still in dispute. Low resolution carbon isotope records prior to this event also limit the construction of a Middle Permian chemostratigraphic framework and global or local stratigraphic correlation, and hence limit our understanding of carbon cycle and environmental changes. To investigate these issues, we analyzed the ¹³C_org values from the Middle Permian chert-mudstone sequence (Gufeng Formation) in the Lower Yangtze deep-water basin (South China) and compared them with published records to build a chemostratigraphic scheme and discuss the underlying environmental events. The records show increased δ¹³C_org values from late Kungurian to early Guadalupian, followed by a decrease to the late Wordian/early Capitanian. The early-mid Capitanian was characterized by elevated δ¹³C_org values suggesting the presence of the “Kamura Event”: an interval of heavy positive values seen in the δ¹³C_carb record. We propose that these heavy Capitanian δ¹³C values may be a response to a marked decline in chemical weathering rates on Pangea and associated reduction in carbonate burial, which we show using a biogeochemical model. The subsequent negative δ¹³C excursion seen in some carbonate records, especially in shallower-water sections (and in a muted expression in organic carbon) coincide with the Capitanian mass extinction may be caused by the input of isotopically-light carbon sourced from the terrestrial decomposition of organic matter.  相似文献